Large Surface Area is Key to a Valuable Adsorbent

Why is surface area key to a quality adsorbent?

Before we talk about surface area it’s helpful  to understand how adsorption works.

Adsorbents work by adsorbing liquids or vapors into pores on their surface.  The adsorption process doesn’t truly absorb the vapor or liquid that’s running through it (meaning the the liquid or vapor isn’t turned into a solid with the adsorbent),  rather molecules from the vapor or liquid are adsorbed and thus they get stuck on to the adsorbent.  In short an adsorbent acts like a magnet.

The pores on an adsorbent are where adsorbed molecules are kept.  The pores can have diameters between a couple of nanometers to hundreds of nanometers.  The purpose of the pores is to not only store molecules but sometimes to separate certain molecules by size.  The pore sizes can differ by nanometers or Angstroms (1 Angstrom = 1/10,000,000,000th of a meter) so you can separate liquids and gases at a molecular level.

For example if you wanted to separated methane from water you would use a 3A molecular sieve because the pore size on 3A is 3 Angstrom.  Water molecules have diameters up to 2.9 Angstrom and methane molecules have diameters up to 3.8 Angstrom.   The molecular sieve adsorbs the water and doesn’t adsorb the methanol thus separating the two molecules from one another.

Surface area measures how much exposed area there is on solid objects.  It’s important to distinguish that surface area and volume are not the same.  As long as the width, length, and height of an object remain the same the volume will never change.  Surface area, on the other had, can change if you break the object into smaller pieces.  See the example with the cube below.

Surface Area

Surface Area of a Cube = l*w*6

Volume of a Cube = l*w*h

 

 

Cube Length: 10mm

 Cube Width: 10mm

 Cube Height: 10mm

 

 

Cube Volume = 10*10*10=1,000mm³

 Cube Surface Area = 10*10*6=600mm²

The volume of an object will remain the same, but surface area can expand.  For example if you break the cube above into 5 parts you would find the following.

 

 

 Length: 10mm

  Height: 10mm

  Width: 2mm

Number of Cube Shaped Boxes: 5

 

Cube Surface Area:

 (2*10*10) + ( 4*2*10)*5=1,400mm²

 Cube Volume: (2*5)*10*10=1000mm³

 

By breaking the cube up into smaller sections, the surface area of the cube increases while the volume remains constant.

Surface area in adsorbents can be large.  1 gram of activated carbon for example has a surface that’s usually around 500m²

The pores on most adsorbents go only a few molecules deep so what you need is a lot of pores if you want to adsorb a lot of material.  Since pores are on the surface that is why you need a lot of surface area.  More surface area means more pores which means more liquid/gas is adsorbed.

 

Sources:

Size of methane molecule,  Slide 16 http://www.epa.gov/lmop/documents/pdfs/conf/12th/gladstone.pdf

Size of water molecule http://www.mc3cb.com/pdf_chemistry/What%20is%20the%20diameter%20of%20a%20water%20molecule.pdf

 

 

   

6 Precautions to Consider While Dehydrating Ethanol

 

Purifying ethanol requires running your distilled ethanol through molecular sieve beds in order to produce over 99% pure ethanol.  In order to dehydrate ethanol thoroughly most plants require that you have ten’s if not hundred’s of thousands of pounds of sieve installed in your vessels.

Making a significant mistake here could be hazardous to your co-workers and it could cost your plant a lot of money if you end up rolling your beds or if you have to shut down the vessels for awhile so here are six precautions to be aware of when running your sieve beds.

1. Watch the temperature – The adsorption process creates a lot of heat energy; do not let temperatures exceed 600 degrees Fahrenheit at any time.
2. Start the dehydration procedure with 200 proof ethanol, if you do not have 200 proof ethanol available, use extra caution until a stream with low water content is available for recirculation.
3. Avoid massive slugs of liquid, these can stir the bed.  Liquids may need to be drained while you are adding the wet feed.
4. Avoid rapid pressure fluctuations, these can cause bumping or lifting in the bed.  Pressure is normally released in order to control temperature.  Be aware that as sieve and ethanol/water streams are in contact with one another intermolecular frictional heat can occur.  Heat releases of up to 1,800 BTUs/lb of adsorbed water and 700 BTUs/lb  of adsorbed ethanol can occur.
5. Watch out for hot spots on the bed.  This can be avoided by having a recirculating feed rate that is high enough to maintain a vigorous flow throughout the sieve beds.
6. Make sure you purge the air.  Ethanol is a flammable vapor and it is running through your beds at high temperatures and in the presence of oxygen.  Purging the air can prevent fire hazards.

Great Biofuel Potential For A Non-Edible Plant

What is Arundo Donax?

Arundo Donax is a large cane plant that is native to Asia and parts of Africa.  It is currently showing great potential as a biofuel producing plant, and as a feedstock for producing cellulosic ethanol.  Despite being native to these portions of the world humans have brought it to Europe and North America, showing that it can thrive in versatile climates.

The stem of the Arundo Donax plant is very durable and sturdy and has been used throughout human history to make fishing poles, walking sticks, and many different types of flutes.  Currently they are used to make the reeds for woodwind instruments like the clarinet, saxophone, oboe, and bassoon, but recent studies are showing the potential this plant has to be converted into biofuel.

Arundo Donax has great biofuel potential because of how large the plant is and how fast it can grow.  Arundo Donax grows to heights between 20 and 33 feet tall on average, and can be harvested twice a year per field it is grown on.  Large amounts of fertilizer are NOT needed to grow this plant, and additionally it is also resistant to biotic and abiotic stresses.   This means it does not require a lot of pesticide thus saving farmers or growers of this plant a considerable amount of money.

Arundo Donax has also shown to offer protection against soil erosion and land degradation, and it even has even adapted to grow in saline (salt) land and water.  This ability to grow in harsher conditions and on harsher lands means that Arundo Donax will not need fertile land that is required to grow food crops, another major benefit.

Arundo Donax yields approximately 8,000-8,400 BTU’s of energy per pound, and about 20-25 tons of the plant can be produced per acre.  These energy yields plus its ability to grow in difficult areas makes this plant a great choice for producing biofuel.

Arundo Donax is already beginning to be applied to biofuel production.  Midway through 2012, construction on the largest cellulosic ethanol facility in the world will be completed in Italy.  The Crescentino Plant will be able to produce over 13 million gallons of cellulosic ethanol a year.  The primary feedstock for this plant will be Arundo Donax.

As the world continues to look towards alternative forms of energy, Arundo Donax looks to be another potential and realistic source of alternative energy.

 

Sources:

http://www.chemicals-technology.com/projects/mg-ethanol/

http://plants.usda.gov/java/profile?symbol=ardo4

http://www.biggreenenergy.com/default.aspx?tabid=4269

 

The Steam-Methane Reforming Process Purifies Hydrogen

Hydrogen, the most abundant element in the Universe (also the lightest) is actually rare to find in a pure form here on Earth.  This is due to hydrogen’s willingness to bond with other atoms and molecules.  Despite its abundance it needs to be separated from these other atoms and molecules in order to be available in a pure form.

Hydrogen is useful to humans and is useful in some important industries.   Pure hydrogen is primarily used to make ammonia (which is in turn used to make fertilizer) and methanol (which is usually turned into fuel).  However it needs to be separate from all of the atoms and molecules it likes to bond to in order to be of any industrial use to humans.

95% of purified hydrogen produced today is made from the Steam-Methane Reforming Process.  This process produces hydrogen from a hydrogen generating source, this is usually natural gas or oil, however other sources can be used.

Molecular sieve’s role in producing hydrogen doesn’t occur until the end of the steam-methane reforming process.  Before molecular sieve gets used the feed stock(most likely natural gas) must go through a hydrodesulfurization process, a steam reforming process, a heat recovery process and a CO conversion process.  These processes further breakdown the complex molecular structure of the feedstock preparing it for the final stage for hydrogen purification.

The final stage in purifying hydrogen is to use a Pressure Swing Adsorption (PSA) process.The PSA process will use either a 5A molecular sieve, which is usually used to create high purity hydrogen or a 13X molecular sieve to adsorb larger hydrocarbons and other impurities if they are there.

5A  specializes in separating straight and branch chained hydrocarbons from one another.  13X molecular sieve will specialize in removing any additional C02 or NH3 if there is any remaining at this point, it will depend on what you used as a feed stock.

There are over 200 Hydrogen producing plants in the world, most of them should be listed in the link below.  Hydrogen plays an important role in various industrial and scientific applications and molecular sieve plays an important role in making it pure.

 

List of Hydrogen Plants: http://bit.ly/wsYzKM

 

Sources:

http://www1.eere.energy.gov/hydrogenandfuelcells/production/natural_gas.html

 

Molecular Sieve Basics: Crystals Help Determine the Pore Size of Molecular Sieve

This article is a kind of a continuation on an article we wrote in 2011 that discusses the pores sizes of molecular sieve.

Molecular sieve are crystalline metal aluminosilicates that belong to the zeolite family.  That means that the molecules and atoms that make up a molecular sieve are made out of alumina, silicon, and oxygen and because they are crystalline they have a strong degree of order in the way they are laid out.

Molecular sieves specialize in separating very small molecules and atoms apart from one another.  Being part of the zeolite family, molecular sieve has a three dimensional network of pores which can adsorb molecules of a specific size.  The pores on a molecular sieve is what makes sieve special, this is because they can separate any substance down to the 1/10,000,000,000th of a meter, or an Angstrom.  There are four standard pore sizes that a molecular sieve can have:

• 3A, 3 Angstrom pore size
• 4A, 4 Angstrom pore size
• 5A, 5 Angstrom pore size
• 13X, 10 Angstrom pore size (depending on the manufacturer the pore size may be either 8 or 9 Angstrom)

The pores on molecular sieve could have one of two structure types: A structure or X structure.  3A, 4A, and 5A are made from an A structure while 13X is made from an X structure.  The A structure is smaller and more square-shaped than the X structure which is larger and circle shaped.

Aluminum Hydroxide, Sodium Hydroxide, Sodium Bicarbonate, and clay are used in the sieve manufacturing process, when the process is created this combination of material will make 4A molecular sieve when created with a type A structure or 13X molecular sieve when created with a type X structure.

3A and 5A molecular sieve are made once they are ion exchanged with the originally cre

ated 4A sieve.  4A molecular sieve is ion exchanged with potassium to create 3A sieve, the potassium molecules are larger than the sodium molecules they were exchanged with shrink the pore size.  5A sieve is created when 4A sieve is ion exchanged with calcium, calcium molecules are exchanged in a 1:2 ratio.  Every calcium molecule removes two sodium molecules thus increasing  the size of the pore.

The various pore sizes of molecular sieve offer a great variety of services to anyone looking to separate different combinations of molecules from one another.